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Materials That Give

MIT News; iStock
MIT researchers use computing in their search for creative, macromolecular solutions to problems at the interface of chemistry, medicine, biology, and materials science.

When engineers design materials for protective equipment, electronics, vehicles, or consumer products, they face a difficult balancing act: materials need to be both strong and resistant to sudden impacts. Traditional plastics often crack or fail when exposed to high-speed forces because they cannot absorb enough energy before breaking.

The MIT researchers discovered a surprisingly effective solution. Rather than making plastics more rigid, they intentionally introduced weak molecular links, known as cross-linkers or mechanophores, throughout the material. When the material experiences a sudden impact, these strategically placed weak bonds break first, absorbing energy and preventing larger cracks from spreading through the structure.

Using this approach, the team substantially improved the ballistic impact resistance of common materials including polystyrene and styrene-butadiene-styrene rubber. In testing, the modified polymers absorbed much more energy and showed significantly less damage than conventional versions of the same materials.

The discovery could lead to tougher consumer products, more durable protective materials, improved vehicle components, and longer-lasting rubber products. The researchers are now exploring whether the strategy can be extended to other widely used polymers, including latex and tire materials.

MIT's research computing and analytical infrastructure supported the modeling, data analysis, imaging, and interpretation needed to understand how energy moves through these materials during impact and why the new designs perform so effectively.

Jeremiah A. Johnson
Thomas Guertin Professor of Chemistry; Member, Koch Institute for Integrative Cancer Research, MIT
Keith A. Nelson
Haslam and Dewey Professor of Chemistry, MIT

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